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ASTM D-2000 Standard Elastomer Specification

One the most reference elastomer standards is the 'Standard Classification System for Rubber Products in Automotive Applications' published by the American Society of Testing and Materials (ASTM), or, more commonly, the ASTM D-2000 specification.  Although obviously developed with the automotive industry in view, this standard has become perhaps the most frequently referenced standard for rubber products in general, and for good reason -- it is one of the most direct and simplest ways to define rubber/Elastomer Physical proprties as they pertain to general application requirements.

Because of its popularity, consumers and others are often confronted with an ASTM D-2000 callout that reads something like 'ASTM D-2000-99 M2BG714-B14-EA14-EF11-EF21-EO14-EO34-F17.'   Although this can appear rather foreboding to those not technically informed on rubber chemistry and properties, it is actually fairly simple to decipher. 

Using the aforementioned sample code, the individual elements of the D-2000 standard are as follows:

Specification Number

ASTM D-2000-99 M2BG714-B14-EA14-EF11-EF21-EO14-EO34-F17

American Society of Testing and Materials primary specification reference number; sometimes abbreviated to "D2000".

Revision

ASTM D-2000-99 M2BG714-B14-EA14-EF11-EF21-EO14-EO34-F17

Indicates the revision (year) of the standard.

Units (Metric/English)

ASTM D-2000-99 M2BG714-B14-EA14-EF11-EF21-EO14-EO34-F17

If present, the 'M' indicates Metric units; otherwise, English measurements are indicated.

Grade

ASTM D-2000-99 M2BG714-B14-EA14-EF11-EF21-EO14-EO34-F17

Grades 2 and up indicate additional requirements per Table 6 of the D2000 specification (see Suffix Requirements below).

Type (Heat Resistance)

ASTM D-2000-99 M2BG714-B14-EA14-EF11-EF21-EO14-EO34-F17

Indicates high temperature resistance as follows:

       ·A =  70°C/158°F
·B = 100°C/212°F
·C = 125°C/257°F
·D = 150°C/302°F
·E = 175°C/347°F
·F = 200°C/392°F
·G = 225°C/437°F
·H = 250°C/482°F

                 Ref: ASTM D573

Typical Type/Class - Elastomer
Chemical Group Associations

ASTM D-2000-99 M2BG714-B14-EA14-EF11-EF21-EO14-EO34-F17

The standard does not directly specify rubber compounds or chemical groups (e.g. Neoprene, Buna-n, etc.).  Rather, it sets forth Type and Class (Temperature and Oil Resistance) criterion ("BG" in sample) that, in turn, narrow the field of options based on application requirements.  However, for reference only, D2000 lists the following typical associations between Type-Class designations and elastomer groups:

        ·AA - Butyl (polybutadiene), SBR, Natural,
          Polyisoprene, Reclaimed rubber
·AK - Polysulfides
·BA - Butyl, EPDM (Ethylene Propylene)
·BC - Neoprene (Chloroprene)
·BE - Neoprene (Chloroprene)
·BF - Buna-N (Nitrile, NBR)
·BG - Buna-N (Nitrile, NBR), Urethanes
·BK - Buna-N (Nitrile, NBR)
·CA - EPDM (Ethylene Propylene)
·CE - Hypalon (Chlorosulfonated 
         Polyethylene)
·CH - Buna-N (Nitrile, NBR), ECH
          (Epichlorohydrin)
·DA - Ethylene Propylene
·DF - Polyacrylate
·DH - Polyacrylate, HNBR
·EE - Vamac (Ethylene Acrylic, AEM)
·EH - Polyacrylate (ACM)
·EK - FZ
·FC - Silicone (high strength)
·FE - Silicone
·FK - Fluorosilicone
·GE - Silicone
·HK - Viton™ (Fluoroelastomers)
·KK - Perfluoroelastomers

             Class (Oil Resistance)

ASTM D-2000-99 M2BG714-B14-EA14-EF11-EF21-EO14-EO34-F17

Indicates oil resistance class by maximum volume swell as follows:

 

           · A - No Requirement 
           · B - 140% 
           · C - 120% 
           · D - 100% 
           · E -  80% 
           · F -  60% 
           · G -  40% 
           · H -  30% 
           · J -  20% 
           · K -  10% 


           Ref: ASTM D471

 

Hardness

ASTM D-2000-99 M2BG714-B14-EA14-EF11-EF21-EO14-EO34-F17

Shore A Durometer x 10; e.g. 7 in the example indicates 70 Shore A hardness.  Ref: ASTM D2240

Tensile Strength

ASTM D-2000-99 M2BG714-B14-EA14-EF11-EF21-EO14-EO34-F17

Stated in PSI (pounds per square inch) or MPa (megapascals), depending on whether English or Metric Units are indicated (see above).  PSI can be converted to MPa by dividing by 145, or, conversely, MPa values can be multiplied by 145 to obtain PSI.  Tensile strength in the sample is 14 MPa or 2,031 PSI.  Ref: ASTM D412

Suffix Requirements (Alpha)

ASTM D-2000-99 M2BG714-B14-EA14-EF11-EF21-EO14-EO34-F17

Indicates tests and related criteria for various elements like specific aging, fluid compatibility tests.  Each element is cited by an alpha code (below) indicating a particular property followed by a numeric code (right) that specifies test criteria (e.g. time, temperature, fluid). 


·A  = Heat Resistance; ref: ASTM D573
·B  = Compression Set; ref: ASTM D395
·C  = Ozone or Weather Resistance; ref:
         ASTM D1171
·EA = Fluid Resistance (Aqueous); ref:
           ASTM D471
·EF = Fluid Resistance (Fuels); ref: ASTM
          D471
·EO = Fluid Resistance (Oils and 
           Lubricants); ref: ASTM D471
·F  = Low Temperature Resistance; ref:
         ASTM D2173
·G  = Tear Resistance
·J  = Abrasion Resistance
·M  = Flammability Resistance
·P  = Staining Resistance
·Z  = Special Requirements

Suffix Requirements (Numeric)

ASTM D-2000-99 M2BG714-B14-EA14-EF11-EF21-EO14-EO34-F17

Testing parameters and related details are further specified by the numeric component of Suffix codes, including test temperatures as follows:

         Suffix Letters A,B,C,EA/F/O,G,K,L

         · 1 =   73°F / 23°C
         · 2 =  100°F / 38°C 
         · 3 =  158°F / 70°C 
         · 4 =  212°F / 100°C 
         · 5 =  257°F / 125°C 
         · 6 =  302°F / 150°C

Suffix Letter F

         · 4  =  -13°F / -25°C 
         · 5  =  -31°F / -35°C 
         · 6  =  -40°F / -40°C 
         · 7  =  -58°F / -50°C 
         · 8  =  -67°F / -55°C 
         · 9  =  -85°F / -65°C 
         · 10 = -103°F / -75°C

ASTM D2000 does not apply to thermoplastic rubbers.  It does apply, however, to compounds including reclaimed rubber.

All values (tensile, hardness, heat and fluid resistance, etc.) relate to ASTM standardized test procedures.



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